出典:Wiktionary
出典:Wikipedia
出典:『Wikipedia』 (2011/06/09 00:06 UTC 版)
In chemistry, chloryl refers to the red-colored cation having the chemical formula ClO+
2. It is polyatomic ion, structurally identical to chlorite and having the same chemical formula but with chlorine in the +5 oxidation state rather than +3. In chloryl, the two oxygen atoms oxidize the central chlorine atom, forming one double covalent bond each, and another elmement or ion oxidizes the chlorine further, leaving the chlorine with one electron pair. (In chlorite, one oxygen atom forms a double covalent bond with the central chlorine atom, and another oxygen atom forms a single bond with the chlorine atom and an ionic bond, or, more rarely, another single covalent bond). Chloryl is isoelectronic with sulfur dioxide.. Chloryl compounds, such as FClO2 and [ClO2][RuF6] are all highly reactive, and react violently with water and most organic compounds.