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出典:『Wikipedia』 (2011/05/02 03:19 UTC 版)

英語による解説

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Wakefieldite ((La, Ce, Nd, Y) VO₄) is an uncommon rare earth element mineral. There are four main types of wakefieldite- wakefieldite-(La), wakefieldite-(Ce), wakefieldite-(Nd), and wakefieldite-(Y), depending upon the dominant rare earth metal ion present. Wakefieldite has a Mohs hardness ranging from 4-5. Wakefieldite forms crystals of tetragonal structure. In terms of crystal structure, it is the vanadate analog of the rare earth phosphate mineral xenotime. Unlike xenotime, it is more favorable for wakefieldite to contain the lighter rare earth elements over the heavier ones. Due to the lanthanide contraction, the heavier rare earths have smaller ionic radii than the lighter ones. When the phosphate anion is replaced by the larger vanadate anion, the tetragonal crystal system preferentially accommodates the larger light rare earth elements.