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出典:『Wikipedia』 (2011/02/14 14:25 UTC 版)

英語による解説

引用

An ansa-metallocene is a type of organometallic compound containing two cyclopentadienyl ligands that are linked by a bridging group such that both cyclopentadienyl groups are bound to the same metal. The link prevents rotation of the cyclopentadienyl ligand and often modifies the structure and reactivity of the metal center. Some ansa-metallocenes are active in Ziegler-Natta catalysis, although none are used commercially. The term ansa-metallocene (ansa being Greek for "handle") was coined by Lüttringhaus and Kullick to describe alkylidene-bridged ferrocenes, which were developed in the 1950s.