英和和英

出典:『Wikipedia』 (2011/05/08 09:36 UTC 版)

英語による解説

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Arsole, also called arsenole or arsacyclopentadiene, is an organoarsenic compound with the formula C₄H₄AsH. It is classified as a metallole and is isoelectronic to and related to pyrrole except that an arsenic atom is substituted for the nitrogen atom. Whereas pyrrole molecule is planar, arsole molecule is not, and the hydrogen atom bonded to arsenic extends out of the molecular plane. Arsole is only moderately aromatic, with about 40% the aromaticity of pyrrole. Arsole itself has not been reported in pure form, but several substituted analogs called arsoles exist. Arsoles and more complex arsole derivatives have similar structure and chemical properties to those of phosphole derivatives. When arsole is fused to a benzene ring, this molecule is called arsindole, or benzarsole.