英和和英

名詞

recoordination (usually uncountable, 複数形 recoordinations)

1. (化学) A second or subsequent coordination (following dissociation)
   • 2015 April 29, Tanja M Laine et al., “A Dinuclear Ruthenium-Based Water Oxidation Catalyst: Use of Non-Innocent Ligand Frameworks for Promoting Multi-Electron Reactions”, in Chemistry (Weinheim an Der Bergstrasse, Germany)^[1], volume 21, DOI:10.1002/chem.201406613:

     From the generated formal [(L)Ru 2 III,III (pic) 6 (OH 2 )] + intermediate, one picoline ligand can dissociate from the Ru center housing the “hydroxide” ligand (structure A in Figure  8 ), which is concomitant with recoordination of the pyrazole nitrogen to the Ru center.